In Traditional Chinese Medicine (TCM), Bai Shao belongs to the 'Tonic herbs for Blood Deficiency' category. Tonic herbs are used for patterns of Deficiency, when one lacks one of the 'Four Treasures' (Qi, Blood, Yin and Yang). Blood tonics tend to be bitter-sweet with either a Warm or neutral nature. Because the Liver stores Blood, all Blood tonics enter that Organ's Channel.
As suggested by its category Bai Shao is Neutral in nature. This means that Bai Shao typically doesn't affect the balance in your body. Balance between Yin and Yang is a key health concept in TCM. Eating too many "Hot" (Yang) ingredients can lead to an imbalance whereby one has a Yang Excess. The inverse is true as well: too many "Cold" (Yin) ingredients can lead to a Yin Excess. The Neutral nature of Bai Shao means that you don't have to worry about that!
Bai Shao also tastes Bitter and Sour. The so-called 'Five Phases' theory in Chinese Medicine states that the taste of TCM ingredients is a key determinant of their action in the body. Bitter ingredients like Bai Shao tends to have a cleansing action on the body by clearing Heat, drying Dampness and promoting elimination via urination or bowel movements. On the other hand Sour ingredients help with digestion and restrain abnormal discharges of Fluids from the body, such as diarrhea or heavy sweating.
The tastes of ingredients in TCM also determine what Organs and Meridians they target. As such Bai Shao is thought to target the Liver and the Spleen. In TCM the Liver is often referred as the body's "general" because it is in charge of regulating the movements of Qi and the Body Fluids. It also takes a leading role in balancing our emotions. The Spleen on the other hand assists with digestion, Blood coagulation and Fluids metabolism in the body.